A strategy to design highly efficient porphyrin sensitizers for dye-sensitized solar cells.

نویسندگان

  • Yu-Cheng Chang
  • Chin-Li Wang
  • Tsung-Yu Pan
  • Shang-Hao Hong
  • Chi-Ming Lan
  • Hshin-Hui Kuo
  • Chen-Fu Lo
  • Hung-Yu Hsu
  • Ching-Yao Lin
  • Eric Wei-Guang Diau
چکیده

We designed highly efficient porphyrin sensitizers with two phenyl groups at meso-positions of the macrocycle bearing two ortho-substituted long alkoxyl chains for dye-sensitized solar cells; the ortho-substituted devices exhibit significantly enhanced photovoltaic performances with the best porphyrin, LD14, showing J(SC) = 19.167 mA cm(-2), V(OC) = 0.736 V, FF = 0.711, and overall power conversion efficiency η = 10.17%.

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عنوان ژورنال:
  • Chemical communications

دوره 47 31  شماره 

صفحات  -

تاریخ انتشار 2011